|
|Section2= |Section3= |Section7= |Section8= }} Ammonium tetrathiomolybdate is the chemical compound with the formula ()2MoS4. This bright red ammonium salt is an important reagent in the chemistry of molybdenum and has been used as a building block in bioinorganic chemistry. The thiometallate anion has the distinctive property of undergoing oxidation at the sulfur centers concomitant with reduction of the metal from Mo(VI) to Mo(IV). ==Preparation and structure== The salt contains the tetrahedral ()2− anion. The compound is prepared by treating solutions of molybdate, ()2− with hydrogen sulfide in the presence of ammonia: :()2() + 4 H2S → ()2() + 4 H2O 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「ammonium tetrathiomolybdate」の詳細全文を読む スポンサード リンク
|